Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

نویسندگان

  • Taisuke Tokunaga
  • Takeshi Yatabe
  • Takahiro Matsumoto
  • Tatsuya Ando
  • Ki-Seok Yoon
  • Seiji Ogo
چکیده

We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

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عنوان ژورنال:

دوره 18  شماره 

صفحات  -

تاریخ انتشار 2017